Student qualifications are added to a student’s contact record. Assuming the qualification is set up (under publish>options) you can it to a student by editing the contact, scrolling to the bottom and select the relevant qualification.
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If you need to add a new Qualification option because you don’t see the Qualification available in the lookup list when attempting to add it to the contact you can add one in Publish>Options>Qualifications
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When adding Australian National Qualifications, if you notice that your preferred ‘Program Identifier’ does not appear in the list then let us know - perhaps training.gov.au have updated the packages since our last update of the Qualifications list - rather than you waiting we can add it for you ;-).